You cannot add additional containers to the Couchbase Server Pods managed by the Operator. I’d ask what you are trying to accomplish, as there might be alternatives.
If you need Client access (Sdk) then you need to use external DNS. If you need just API/UI access, you can use ExposedFeatureTemplates under Networking and expose the AdminUI.
Also, in 2.6.1, which just released yesterday, we made generally available a new Cloud Native Gateway, which exposes a single point gRPC gateway that can be load balanced via an Ingress.